Multipurpose Wetting Agent
Cold Fire™ is an environmentally friendly fire extinguishing agent that puts out ANY fire faster, safer, with less water, less damage to property, and less risk to firefighters. Cold Fire cools 21 times faster than water, and works to remove heat and the fuel sources from the fire tetrahedron, preventing reignition. Completely 'green' and non-toxic, Cold Fire puts out any Class A, B, D, or K fire, hydrocarbons or polar solvents, as well as metals, tires, and asphalt. Also suppresses vapors and helps to remediate spills.
After Cold Fire™ is applied to a structure it remains wet for forty-five minutes. There is field experience indicating that once dry there may be extended protection. Gels can dry in a few hours and become ineffective unless rehydrated.
by Dr. Addison Bain, Ph.D.
The purpose of this booklet is to provide interested parties pertinent information about the product calledCOLD FIRE®. The primary focus includes those entities responsible in the management of wildland fires.
COLD FIRE®(CF) is one of the products produced by FireFreeze Worldwide, Inc. in Rockaway, New Jersey. CF has been used as a firefighting agent for local fire departments, the racecar industry, as a cool-down agent for plumbers/welders and for wildland firefighting interests in other countries. Seeing CF as a valuable tool for use in wildland firefighting the challenge was undertaken to work with the US Forestry Service (FS) to obtain their approval, with the objective of getting CF on the FS Qualified Product List (QPL).
The policy of federal agencies is to use only qualified products (NFES 2724 chapter 12). Although a significant amount of testing of CF had been performed by a number of US and Canadian laboratories, this was not an acceptable substitute by the FS who use a specific test protocol. CF is a very unique product, derivative of German origin, constituting a well-formulated mix of several plant species. Aside from the plant extracts are the mineral and salt makeup naturally adsorbed from the respective unique soils. No chemicals are added.
The product does not contain any phosphate or bromine derivatives, or polymers common to many retardant and extinguishing agents. It is the discovery that the final product mix when blended with water takes on special characteristics to enhance the overall efficiency of controlling Class A, Class B and Class D fires that make CF an effective, safe and environmentally friendly agent.
TEST PROGRAM PRIOR TO THE QPL
The following outlines the timing, sources and type of testing done in accordance with regulatory specifications and requirements.
CF successfully passed the performance criteria in all cases.
1993, USTC/Biological Services, eye and dermal irritation, acute oral toxicity, aquatic toxic on rainbow trout, water flea and alga. Per EPA Health Effects Test Guidelines.
1994, UL Inc., Certificate granted 10/1996. Class A & B per NFPA 18, Standard for wetting agents.
1995, UL of Canada. Class A & B certifications.
1996, SGS US Testing Co. Inc., Aluminum and carbon steel corrosion rate evaluation per 49 CFR 173.120.
1996, USGS, acute dermal toxicity study on rabbits, skin sensitization study on Guinea pigs.
1997, SGS, acute inhalation toxicity on test animals (rats).
1998, EPA Significant New Alterative Policy (SNAP) program, acceptable substitute for the Halons.
1998, Intertek Testing Service, thermal surface cool-down comparisons for metals and glass.
1999, UL of Canada, CF testing for Class D performance.
TESTING PROGRAM IN SUPPORT OF THE QPL
The Forest Service Classifies the Fire Chemicals as:
Long-Term Fire Retardant
Class A Wildland Fire Foam
CF was evaluated as a water enhancer to FS specification 5100-306a (l2/02).
The evaluation program was initiated in May 2003.
CF was approved and initially added to the QPL on April 5, 2005.
It is noted: CF is not a Gel as are the other water enhancers listed.
Testing was done at the Missoula Technology Development Center (MTDC) in Missoula, Montana as well as back-up testing for correlation at the San Dimas facility in California.
The CF concentrate, as well as the recommended field mixture, was evaluated. The outdoor storage consisted of one year subject to a freeze - thaw environment. Many of the test parameters were repeated in order to demonstrate no detrimental effect after long-term storage. Special testing was done by outside labs at Pacific Metallurgical Company, Stillmeadow Inc., U.S. Geological Survey and Underwriters Laboratory, Inc.
FS TESTING POST INITIAL QPL STATUS
The QPL listing of 4/5/05 approves CF for helicopter bucket and ground engine applications. Since then specialized tests of CF with aluminum coupons has proven successful. Therefore the QPL was updated 2/6/06 to reflect conditional approval for fixed-wing air tanker and single engine air tanker (SEAT) applications. The remaining tests involved the evaluation of CF for magnesium corrosion (uniform and intergranular), a requirement for the fixed-tank helicopter application. CF is the only water enhancer approved for this application.
The Bureau of Land Management sponsors field operational evaluations for QPL listed water enhancers. The evaluations are on going during the fire seasons. The principal goal is to evaluate, and compare, the effectiveness of water enhancers, using aerial applications (SEAT) to support suppression tactics in grass, brush, and timber fuel types.
Some state agencies such as the California Division of Forestry (CalFire) support the field evaluation of products for the helicopter bucket and ground engine applications during respective fire seasons.
The author suggests there are really two aspects of a field evaluation.
The research laboratory of FM Global, one of the worlds largest property insurance and risk management organizations, has evaluated CF. They have found CF acts as a surfactant encouraging the formation of fine droplets when sprayed on a fire providing better cooling, good penetration and more rapid extinguishment. A special formulation is effective as an additive for anti-freeze fire suppression applications. FM Global found CF "has a remarkably high specific heat at temperatures between 32 and 68 degrees F explaining its good cooling properties."
The CF enhances the water viscosity to a certain degree. Viscosity is significant for aircraft water drops to help hold a tight pattern of the water mix. FM Global also found that CF spreads very rapidly over surfaces of mineral oil and other liquid fuels. Thus they would anticipate that it would be a very effective extinguishing agent for Class B fires. These types of evaluations continue to enhance the understanding of the properties of CF , in this case by a renowned certification organization (formally Factory Mutual).
Rubber tire fires have been notoriously difficult to extinguish. In 2003 under the auspices of Underwriters Laboratory the Michelin Tire Company conducted tests to develop data relative to the fire protection of rubber tires stored on pallets in a warehouse. A typical warehouse overhead sprinkler system was used. Ceiling height was 30 feet. A test with water only was done to establish a reference point.
A one-minute average air temperature of 1,600 deg. F and a 1,000 deg. F for overhead steel structural components was the test criteria. With water only, the steel beam temperature above ignition exceeded 1,000 deg. F. Using an aqueous solution consisting of 3% CF the maximum temperature was 379 deg. F for the one-minute test.
Interesting to note that the water only test had to be put out using a fire hose supplied with a CF mix to prevent destruction of the test facility.
Fire Freeze the manufacturer of CF sponsored the UL testing in 2007 for extinguisher and sprinkler applications.
This test program was a result of the updated requirements imposed by the NFPA.
Water is the most effective fire-suppressing agent known to man. When water is exposed to the flame combustion temperature it vaporizes. The change in phase from a liquid to a vapor under goes a "heat of vaporization" process in which the transition requires the absorption of heat.
For a gallon of water to vaporize it must "suck-up" over two million calories of heat. Thus the cooling process. Applied properly one volume of water will cool 300 volumes of burning fuel. But the trick is to do this effectively and not "waste" a lot of water. One is the firefighter technique; his ability to manipulate the hose nozzle to provide a straight-stream, spray or fog as the situation may dictate is essential. Then comes the science.
For years it has been the challenge of the scientific community to come up with strategies to enhance the capability of water. The use of additives (agents) to reduce surface tension, increase the surface area and regulate droplet size have been investigated. The problem is to have a f product that is not overly toxic or harmful to the environment easy to use in the field and not cost prohibitive.
As such sc products have proven to be satisfactory while others had t< taken off the market.
Water has a surface tension of 73 dynes/cm. CF, like sc foams, can drop that by several factors. This allows the w; molecules to penetrate the fuel more effectively and spread the coverage. There is what is known as fuel limited fire Examples are a burning pile of rubble or a burning pile tires. Tests by the Michelin Tire Company show that CF the deep-seated fire cooling capability needed for fuel-limited situations. Large piles of rubble as a result of post Katrina de up operations have also proven CF unique.
The piles caused spontaneous combustion. Water alone was not efficient putting out the resulting fires. Also very important is its ability to prevent re-ignition of hot spots. The surfactant ingredients in CF go beyond the surface tension reduction by having high affinity for carbon, as demonstrated by the Michelin testing, where tires have a high fraction of carbon. Ingredients in CF provide condensation nuclei to promote droplet formation of the water and increase effectiveness. It is no the breakup of the water droplets to a finer configuration exposes more surface area.
Controlled cooling testing, by Intertek, showed timeline factors of CF versus water in surface/mass cooling comparisons, ranging from 5:1 for glass up to 21:1 for metals. Thus cooling aspect is significant (enhanced by the wetting effect),
During the burning process a chemical chain reaction takes place in which new products form, the key to the reaction that produces fire, an important aspect of the fire tetrahedron (fuel, heat and oxygen are the other aspects). The traditional role for the use of water/agents is to interrupt one or more of these aspects to put out or control the fire. CF goes beyond this relationship as will be discussed.
The influence of CF has been explained up to now in the sense of the resulting physical appearance of its effect in certain applications. However the story goes deeper when we visit what is happening on a chemical/biological basis. The following itemizes these characteristics based on laboratory experimentation.
So what happens when CF is used is actually a simultaneous process involving all its chemical/physical/ biological properties.
There continues to be more interest in the environmental implications of firefighting chemicals.
Fire retardants and suppressants are used extensively for suppression and control of range and forest fires. Each year, fire control agencies utilize millions of gallons of these mixtures on a wide array of ecosystems. These chemicals are often applied in environmentally sensitive areas, which may contain endangered, threatened, or economically significant plant and animal species. The study of the potential impact of these chemicals is on going. It is a very difficult problem in balancing the benefit of the chemical mixture to accomplish its primary mission to control a fire and to minimize the extent of the environmental impact.
Being of common plant origin, CF will meet this challenge.
Please explain the cooling mechanism.
CF absorbs heat, retains it, and then releases it through a diffused moisture-air release. This diffusion release is slow and takes place until the surrounding temperature is reduced below the ignition (flash) point. The tremendous thermal absorption capacity of CF is best demonstrated by the following experiment:
A common white cotton hand towel placed over the experimenters hand is sprayed with CF. A handful of magnesium chips is placed on the towel. A propane cylinder soldering-torch is used to ignite the magnesium. After about one minute the magnesium has burnt and during that time reached a peak temperature ofS,600 degrees E, however leaving the towel still intact, albeit slightly scorched.
Address the specific volume relationship of CF/water and burning fuel volumes.
There is no single statistic to equate the volumetric mix of CF due to all the variable performance parameters that have been observed in the field. The total volume and percentage of CF in the water varies according to the application. Perhaps the best way to address this topic is to cite two examples:
There are concerns about the use of existing firefighting apparatus.
It is added directly into fire truck booster tanks, fixed units, CAF (compressed air foam) machines, injectors, inductors, sprinkler systems, automatic fire extinguishing systems, closed loop systems, water mist systems, hand-held extinguishers, dust collector systems, forestry equipment and firefighting IFEX systems, Bambi-bucket applications and deluge systems.
In UL Certificate of Compliance, UL 2000 Directory for fire fighting agents in accordance with NFPA 18 Standard for Wetting Agents, HYPRO and WS Darley (major equipment manufacturers) confirm that and show CF to be compatible and pumpable through hoses and pumps.
CF can be used in standard firefighting equipment without fear of corrosion or clogging of lines and hoses as is very common when using foams, gels and other high viscosity agents. Before introducing CF it is important to clean the equipment to eliminate residue of these products as CF performance is severely compromised.
In aerial applications there is the problem of shearing of the falling mass that to some degree can be reduced by the addition of thickeners/gums, please comment.
CF breaks down water-tension and molecular bonding.
Accordingly, water no longer falls as attached molecular mass; but semi-separate molecules. This means less air resistance. Field-testing is necessary to address wind drift.
Thickeners made up of polymers and/or gums could cause other problems. Super-absorbent polymers themselves ignite after a certain point. This might cause re-ignition. The issue should be studied further by subjecting these polymers to high intensity temperatures. Similarly some gums, which are not 100% soluble in water, also ignite at certain temperatures.
There appears to be some confusion over your product as it relates to the gels.
Perhaps the best way to address this is that the original FS specification was entitled "Gels and Elastomers." Later the specification was changed to "Water Enhancers."
The products listed on the QPL, in general, use the term gel in their product name thus the reader is led to assume all of the listed products are gels. CF , being relatively new to the FS evaluation program, got caught up in this terminology debacle.
Tell us the use of your product for structure protection.
Normally the process of applying CF mixed with water to a structure enhances the effectiveness of the water. In theory this mixture is effective until the water has evaporated. Field experience is demonstrating that the residual left on the structure, after the evaporation period, may be extending the protective performance.
Based on field evaluations and feedback from users there is evidence that CF is providing various degrees of protection depending on a number of factors such as weather and other conditions. Thus the product may provide a protective barrier from oncoming wildfires for a period of time. The longevity of course would be influenced by wind, rain and the natural biodegradability of the product.
It seems the product would be useful in other countries
Indeed, over the years, countries such as Mexico, Australia and Saudi Arabia have used CF extensively. It is interesting to note that the U.S. and Australia have a
Wildland Firefighting Partnership. The arrangement allows both nations to save lives and property by using personnel and equipment from the other country, thus taking advantage of the countries differing fire seasons.
Please address the apparent reluctance of some agencies to use your product.
Setting the controversy of the Gel nomenclature debacle aside there is a very important aspect to address. There is the unwritten, unspoken code of the tight - brotherhood of firefighters. Fires mean jobs. Fires mean overtime pay. Small independents providing secondary support such as the food and beverage mobile canteens look forward to the fire season, in some cases, for their livelihood. Fires are essential to the ecological process. It has been said, " CF works too good." This is one side of the coin.
The other side of the coin: loss of life, unwanted destruction of property, natural and cultural resources-requires no further elaboration.
Federal policy is founded on certain guiding principles.
That is, the firefighter and public safety is the first priority in every fire management activity. The fire management plans should be based on the best available science.
Water enhancers. CF is the only non-gel water enhancer on the QPL. All others are a very viscous gel formulation. Some come in the form of a powder and need to be mixed with water-a tedious task. The development of the gel was primarily intended as a temporary structure protection for advancing wildland fires. Experiences from many state officials indicate that the gel is not living up to its original expectations and causing many problems in the field, such as clogging up equipment. Gels are very slippery. It has been observed that they can cause detrimental effects on painted surfaces, shingles and related structural materials. The gels, like CF, improve the ability of water to cling to vertical and smooth surfaces.
The FS has issued a precautionary "measure" about the water enhancers as follows:
Class A foams. Now very popular and widely used. Twenty five years ago, foam was a "hard-sell." Although they are on the QPL their use is restricted in that special personnel protective gear needs to be used. They can be irritating to eyes and skin. Foam concentrates typically consist of three major components: a foaming agent, a stabilizer and a surfactant. Foams are thick masses of gas bubbles and water that are used to blanket and smother the fire. Some are corrosive to metals, speed deterioration of sealing materials, and are harmful to the environment in high concentrations. Most post-field operations require the equipment to be flushed with clean water to remove the foam residuals. Care must be taken to prevent cross mixing of various manufacturers products in one system. Foam concentrates exhibit considerable variations in viscosity as a function of temperature. (In the case of the five Class B foams there is the hazard of selecting the wrong one, generating a far greater and more hazardous vapor cloud).
Fire Retardants. A substance that, by chemical or physical action, reduces or slows combustion, thus "retarding" the rate of spread of the flame front. They consist of a mix of water, several chemicals and a coloring agent. The main chemical ingredient is a fertilizer. They are most effective when applied in front of the flame front, not directly on it. So-called long- term retardants contain chemicals, which continue to retard fire even after the water has evaporated.
Forest Service Wildfire Management Policy. The common opinion concerning a forest fire is to allow it to burn and consume the residual fuel on the forest floor and in the underbrush. Experience has shown the forest has a remarkable recovery from such "destruction." Prescribed burns are common to reduce the fuel on certain terrains. However, when advancing fires pose a threat to structures, preserves or people, then the policy is to "control" the fire in a manageable direction or limitation.
COLD FIRE® can be used to accomplish these desires.
The trained firefighter knows about what is called "flashover." In say a house fire where furniture and other household items are heated in a closed space with limited oxygen, there is a build up of pyrolysis products. When these products cannot find enough oxygen to burn, they rise and concentrate near the ceiling. Then if more oxygen enters the room, say from a door opening or someone smashing a window, the unburnt gases ignite in an explosive manner. But in an open forest area sometimes over bare earth and/or in thin air? Here are some interesting stories:
And the bottom line is ... ? Cost is a relative thing that can create a lot of debate. Comparing apples to apples is a challenge. Competition among products must be evaluated from many aspects, including the intended application.
Mixed agent value
Assume the fire department has a rig loaded with 1,000 gallons of water on standby. (The 600-gallon brush truck is common for brush fires). It is the "value" of the water that counts. That is, the labor, energy used, other resources used, maintenance of the rig, overhead, and similar costs that gets the water ready for action, not to mention the cost of getting to the fire scene. Add 5 gallons of CF and the rig is ready to fight a brush fire where the water can then get the best "bang for the buck."
Examples of added value overlooked
COLD FIRE® is now another viable tool in the fire technology package
One of the challenging problems in fighting forest fires is in the method of getting the suppression agent to the fire. For ground engine applications one confronts the difficult, or inaccessible, rugged terrains, such as steep slopes, dense foliage or swamp laden areas. For aerial applications a lot depends on the skill of the pilot for accuracy and timing of the drop. There is the troublesome aspect of the smoke and the very dangerous aspect of the heated air, lowering the air density, affecting aircraft aerodynamics.
Enter the airship. Not a new idea. Their big advantage is the ability to hover near the fire, first as a stationary observation platform. Coordination can be made with the fire commander on the ground to select the best option for an airdrop. On board video fire image coverage, sensors to measure local air density and infrared sensors to locate hot spots are but a few ideas to help with the communication.
The airship would need to employ both the static and dynamic lift features for trim control, as the water/agent drop is a significant ballast release. A snorkel device could be used to load the on-board container (from a body of water). A special holding container would hold the suppression agent to be mixed with the water as is done with the aircraft "water scoopers," for example. A high pressure water jet could be used to not only deliver the mix several hundred feet but to break up the water droplet to a finer mist, an aspect that has been demonstrated to enhance the overall effectiveness of water. Clearly the operation would be managed by an on-board computer controlled system.
The large drawback is the upfront expense of the airship.
It would make sense to design them for multiple uses. That is, a "fire status" mode and say, a "cargo" mode. The latter, for movement of large equipment, and the many other applications proposed in the literature. A flexible bladder, or detachable container, could be used for the fire status mode so that the static lift volume could be increased, perhaps using the ballonet concept.
The use of water with a modest yet adequate CF mix would be very effective for knockdown of the flame front. The noncorrosive, non-clogging features of CF, along with all its other attributes in combination with the airship delivery method would make a fine overall aerial technique for combating the wildland fires.
COLD FIRE PUMPER RATIO CALCULATOR AND EXTINGUISHER REFILL INSTRUCTIONS
To use the Ratio Calculator below simply enter the size of the water tank or amount of gallons currently in the tank and the percentage mix you want to have and it will tell you how many gallons of Cold Fire to be added to the water tank.
Cold Fire Extinguisher Refill Instructions:
1. Invert or turn the extinguisher upside down and release ALL air pressure in the extinguisher
2. Unscrew the extinguisher handle
3. Pour water into the extinguisher: For 2.5 gal= 2.25 gallons, 1.5 gal= 1.25 gallons, 4 ltr= 3.25 liters, 2 ltr= 1.50 liters
4. If Using Regular Cold Fire Solution: Add 2.5 gal- 4 Cups, 1.5 gal- 3 Cups, 4 ltr= 2 Cups, 2 ltr= 1 Cup
5. *** If Using All-Season Cold Fire: Fill the extinguisher 95% full with All-Season DO NOT add water
6. ***Always make sure to leave about 5% of the space for air to pressurize the unit/s. The above measurements take this into account.
7. Screw the extinguisher top back on just hand tight or slightly tighter with a wrench DO NOT tighten as much as possible with wrench
8. Pressurize the unit
First Responder Safety Public Safety Environmental Safety
Cold Fire® is a unique fire suppressant product that should be available in all fire emergencies. Because Cold Fire® absorbs 10 times the BTUs of water and has 6 times the penetrating capability, it allows, for example, a fire fighter to enter and exit a structure much quicker, stay cooler, and to knock down the fire much faster while using 65% less water and no re-igniting. Another important feature, from a safety perspective, is the fact that Cold Fire® is also a thermal barrier product, i.e., it provides a barrier from heat such that it can be applied to skin, clothing, or other objects/surfaces and will prevent heat from penetrating the surface. As well as its unique ability to rapidly cool objects and remove heat from a fire.
Here are the main reasons why many departments are switching exclusively to Cold Fire: Cost Savings!
Cold Fire® is a wetting-agent and has as the following ratings and listings:
“In my 27 years of fire-fighting, no fire-fighting product has impressed me as much as yours. Cold Fire lives up to, if not exceeds, all that was advertised… I feel that Cold Fire will definitely improve our fire-fighting and reduce injuries to our members. This is a product that we will be using more and more in the future.”
Ronald Schnall - Chief, Holbrook Fire Department